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A substructure consisting of rings of different sizes embeds itself seamlessly into a hexagonal structure Photo Credit: Dr. Stefan Förster |
The structure of two-dimensional titanium oxide breaks up at high temperatures by adding barium; instead of regular hexagons, rings of four, seven and ten atoms are created that order periodically. A team at Martin Luther University Halle-Wittenberg (MLU) made this discovery in collaboration with researchers from the Max Planck Institute (MPI) for Microstructure Physics, the Université Grenoble Alpes and the National Institute of Standards and Technology (Gaithersburg, USA), thereby solving the riddle of two-dimensional quasicrystal formation from metal oxides. Their findings have been published in the renowned journal "Nature Communications".
Hexagons are frequently found in nature. The best-known example is honeycomb, but graphene or various metal oxides, such as titanium oxide, also form this structure. "Hexagons are an ideal pattern for periodic arrangements," explains Dr Stefan Förster, researcher in the Surface and Interface Physics group at MLU’s Institute of Physics. "They fit together so perfectly that there are no gaps." In 2013, this group made an astonishing discovery upon depositing an ultrathin layer containing titanium oxide and barium on a platinum substrate and heating it to around 1,000 degrees centigrade in an ultra-high vacuum. The atoms arranged themselves into triangles, squares and rhombuses that group in even larger symmetrical shapes with twelve edges. A structure with 12-fold rotational symmetry was created, instead of the expected 6-fold periodicity. According to Förster, "Quasicrystals were created that have an aperiodic structure. This structure is made of basic atomic clusters that are highly ordered, even if the systematics behind this ordering is difficult for the observer to discern." The physicists from Halle were the first worldwide to demonstrate the formation of two-dimensional quasicrystals in metal oxides.