. Scientific Frontline

Monday, June 19, 2023

Clean, sustainable fuels made ‘from thin air’ and plastic waste

Carbon capture from air and its photoelectrochemical conversion into fuel with simultaneous waste plastic conversion into chemicals. 
Photo Credit: Ariffin Mohamad Annuar

Researchers have demonstrated how carbon dioxide can be captured from industrial processes – or even directly from the air – and transformed into clean, sustainable fuels using just the energy from the sun.

The researchers from the University of Cambridge developed a solar-powered reactor that converts captured CO2 and plastic waste into sustainable fuels and other valuable chemical products. In tests, CO2 was converted into syngas, a key building block for sustainable liquid fuels, and plastic bottles were converted into glycolic acid, which is widely used in the cosmetics industry.

Unlike earlier tests of their solar fuels technology however, the team took CO2 from real-world sources – such as industrial exhaust or the air itself. The researchers were able to capture and concentrate the CO2 and convert it into sustainable fuel.

Although improvements are needed before this technology can be used at an industrial scale, the results, reported in the journal Joule, represent another important step toward the production of clean fuels to power the economy, without the need for environmentally destructive oil and gas extraction.

GE Aerospace runs one of the world’s largest supercomputer simulations to test revolutionary new open fan engine architecture

CFM’s RISE open fan engine architecture.
Image Credit: GE Aerospace

To support the development of a revolutionary new open fan engine architecture for the future of flight, GE Aerospace has run simulations using the world’s fastest supercomputer capable of crunching data in excess of exascale speed, or more than a quintillion calculations per second.

To model engine performance and noise levels, GE Aerospace created software capable of operating on Frontier, a recently commissioned supercomputer at the U.S. Department of Energy’s (DOE) Oak Ridge National Laboratory with processing power of about 37,000 GPUs. For comparison, Frontier’s processing speed is so powerful, it would take every person on Earth combined more than four years to do what the supercomputer can in one second.  

By coupling GE Aerospace’s computational fluid dynamics software with Frontier, GE was able to simulate air movement of a full-scale open fan design with incredible detail.

“Developing game-changing new aircraft engines requires game-changing technical capabilities. With supercomputing, GE Aerospace engineers are redefining the future of flight and solving problems that would have previously been impossible,” said Mohamed Ali, vice president and general manager of engineering for GE Aerospace.

“Predatory bacteria” provide hope for chlorine-free drinking water

The inside of a water pipe
Photo Credit: Krisjtan Pullerits / Lund University

In a unique study carried out in drinking water pipes in Sweden, researchers from Lund University and the local water company tested what would happen if chlorine was omitted from drinking water. The result? An increase in bacteria, of course, but after a while something surprising happened: a harmless predatory bacteria grew in numbers and ate most of the other bacteria. The study suggests that chlorine is not always needed if the filtration is efficient - and that predatory bacteria could perhaps be used to purify water in the future.

Just as human intestines contain a rich bacterial flora, many types of bacteria thrive in our drinking water and the pipes that transport them. On the inside of pipe walls is a thin, slippery coating, called a biofilm, which protects and supports bacteria. These bacteria have adapted to life in the presence of chlorine, which otherwise has the primary task to kill bacteria, particularity bacteria that can make humans sick.  

An ordinary glass of drinking water contains a lot of harmless bacteria. Chlorine, however, which in the studied piping system was added in the form of monochloramine, is not wholly unproblematic.

Climate impact of natural gas often worse than assumed

Dr. Florian Dietrich (blue shirt) and prof. Jia Chen check the measuring systems on the roof of the TUM.
Photo Credit: Andreas Heddergott / Technical University of Munich

Heating and cooking with natural gas often has a greater impact on the climate than commonly believed. This is a conclusion of a new calculation model developed by researchers at the Technical University of Munich (TUM). The difference: the researchers’ model also takes into account the enormous quantities of unused gas released into the atmosphere.

“We wanted to know whether – when gas leakage is also considered – gas or electricity is more climate friendly for heating and cooking,” explains Dr. Florian Dietrich, a researcher at the TUM Associate Professorship of Environmental Sensing and Modeling. In collaboration with researchers at ETH Zurich, the University of Utrecht and the Dutch organization for applied research in natural sciences TNO, the international team used a high-tech measurement station to capture carbon dioxide, methane and carbon monoxide. They also used laser spectrometers for onsite methane measurements. They then combined all variables in a specially designed calculation model. The results were published and verified in a peer review process.

Simple maintenance can reduce hospital Legionella risks

Photo Credit: PublicDomainPictures

Hospital water systems are a significant source of Legionella, resulting in the potentially fatal Legionnaires’ disease – but Flinders University researchers have proven simple maintenance that involves running hot water regularly and flushing the pipes has a huge effect in reducing the risk of the disease.

One of the biggest challenges for Legionella management within large hospital systems is that under unfavorable conditions, Legionella transforms itself into a state (called viable but non culturable – VBNC) that cannot be detected using standard methods.

To understand the extent of the problem, Flinders University researchers conducted the first comprehensive study that quantified all Legionella, including those in the VBNC state, and free-living amoebae from a hospital water system under dynamic flow and temperature conditions.

“We took a different approach because we didn’t know how often the standard method was returning false negative results for Legionella and it’s really hard to determine the optimal management approach if you can’t trust your testing method,” says Flinders University’s Associate Professor Harriet Whiley.

Gravity foundations: A marine-friendly future for wind turbines

Photo Credit: Tom Swinnen

Gravity-base structures may offer a porpoise and dolphin-friendly construction alternative to traditional pile-driven wind turbine foundations, new research suggests.

Marine scientists from Newcastle University investigated short- and long-term impacts of this new wind turbine installation method on cetaceans off Blyth, Northumberland. The response of dolphins and harbor porpoises was investigated using cetacean echolocation recorders over a three-year period, covering one year before, during and after the installation.

The findings revealed that wind turbine installation using gravity-base foundations had no long-term effects on the occurrence of dolphins or porpoises.

“Our findings are important in light of the global expansion of offshore wind farms and the need to find installation methods that have less impact to the marine environment”, says lead author and master’s graduate Kelsey Potlock. “These findings are promising for conservationists, marine environmental managers, and for the future of offshore renewable energy.”

Physicists Have Presented a New Way to Control Wheat Quality

Russia is one of the world's largest grain producers
Photo Credit: Andriy Nestruiev

A team of scientists from the Ural Federal University and the Ural Branch of the Russian Academy of Sciences has tested a new method that can be used to verify whether wheat has been irradiated and how safe the consequences are for consumers. Without documentation and sophisticated equipment, it is difficult to determine whether grain has been treated. Currently, there are methods for testing irradiated products, but they are more expensive and not as accurate, physicists say. The method of verification proposed by the scientists can make the analysis easier and cheaper, because the products themselves will act as an alternative to the detector in the radiation treatment. The study was supported by the Russian Foundation for Basic Research (project № 20-58-26002). The experimental results were published in the journal Radiation Physics and Chemistry.

Ionizing radiation of agricultural products is an effective method of disinfecting and neutralizing harmful microorganisms. This method is widely used in many countries and is approved by international organizations such as the World Health Organization, the Food and Agriculture Organization, and the International Atomic Energy Agency. After irradiation, the product is safe and does not lose its beneficial properties. Moreover, the destruction of harmful microorganisms (for example, mold) can increase the safety of the same wheat for further planting. In Russia, radiation treatment of agricultural products is allowed by law. There are several facilities in the country that use this type of decontamination. However, this type of food decontamination is not as widespread as, for example, in the United States or China.

Saturday, June 17, 2023

Chemistry without detours: TUD researchers introduce a two-step process for producing phosphorus-containing chemicals

Example of a complex biomolecule from the group of functionalized nucleotides, achieved through the method developed by the Weigand Research Group using conventional phosphoric acid.
Image Credit: © Weigand Group

Professor Jan J. Weigand and his team from the TUD Dresden University of Technology have achieved a ground breaking advancement in the production of phosphorus-containing chemicals. In a recent publication in the renowned scientific journal Nature Synthesis, they present an innovative synthesis method that requires only two process steps for the previously complex production of functionalized phosphates. This promising innovation not only contributes to environmental protection but also saves significant time and costs. Furthermore, it offers the industry the opportunity to become less dependent on third countries. The research team has already filed two patents for this new process.

Phosphorus and its compounds are essential components of life and indispensable in our daily lives. In the human body, this element plays a crucial role in energy transfer and numerous cellular functions. Phosphorus compounds are used in fertilizers, detergents, medications, and many other products. Additionally, phosphorus is an essential ingredient in flame retardants, battery electrolytes, and catalysts. On Earth, phosphorus exists exclusively in the form of phosphates. The production of phosphorus-containing chemicals typically involves a complex and energy-intensive multi-step process. Initially, highly toxic white phosphorus (P4) is produced via a redox pathway and then further processed into phosphorus trichloride (PCl3) and other problematic and sometimes highly toxic intermediate products. Phosphorus chemistry based on P4 is associated with significant challenges but plays an indispensable role in the chemical industry due to its great importance.

Diagnosis of rare, genetic muscle disease improved by new approach

Researchers at Washington University School of Medicine in St. Louis have developed an approach that could help doctors distinguish between the many subtypes of limb girdle muscular dystrophy, a rare, genetic muscle disease. With new therapies poised to enter the clinic, identifying the precise subtype is necessary to ensure that people get access to the treatment most likely to benefit them.
Image Credit: ANIRUDH

It’s not easy to distinguish between the dozens of subtypes of limb girdle muscular dystrophy — a rare, genetic muscle disease characterized by weakness in the hips and shoulders that causes difficulty walking and lifting the arms. Until now, determining the subtype has not been critical in caring for patients, because no specific treatments have been available. But gene therapies are on the horizon, and such therapies are targeted to specific genetic variants, so pinpointing the genetic roots of each patient’s disease has taken on a new importance.

In new research, a team at Washington University School of Medicine in St. Louis has developed an approach that could help doctors make more precise diagnoses. The study is published June 15 in The Journal of Clinical Investigation.

Hundreds of genes are associated with limb girdle muscular dystrophy. While genetic testing may identify a handful of rare genetic variants in each patient with the condition, there’s no way to know without painstaking, time-consuming additional experiments which, if any, of those variants is responsible for a patient’s symptoms. Unfortunately, no comprehensive catalog exists yet of all the variants of all the genes linked to limb girdle muscular dystrophy, and whether each of those variants can cause disease or is harmless.

Pharmacy researcher develops intervention for metabolic diseases like diabetes, stroke and heart disease

Photo Credit: Michal Jarmoluk

An investigator with the University of Kansas School of Pharmacy has filed an invention disclosure, part of a provisional patent application with the United States Patent and Trademark Office, for a treatment that could apply to heart disease, stroke and a host of other human diseases related to metabolism.

Liqin Zhao, KU associate professor of pharmacology & toxicology and investigator at the Life Span Institute2, has researched the human ApoE gene for years. A major focus of her work centers on how the ApoE2 variant — one of three major isoforms of ApoE gene — might protect people from Alzheimer’s disease3.

Now, based upon a discovery made during her Alzheimer’s-disease work, Zhao is patenting a way to leverage rhApoE2 to regulate blood lipids. Lipids, like fats and oils, are building materials of life at the cellular level that also are tied to heart disease and other metabolic diseases.

“In essence, we found that rhApoE2 significantly lowered blood levels of a number of ceramides,” Zhao said. “Moreover, rhApoE2 increased blood levels of a variety of ‘good triglycerides’ — triglycerides that contain health-promoting, long-chain polyunsaturated fatty acids such as alpha-linolenic acid, EPA and DHA, and lowered levels of ‘bad triglycerides,’ or triglycerides that contain saturated or monosaturated fatty acids that can impose a cardiovascular risk.”

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