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Highly precise optical absorption spectra of diamond reveal ultra-fine splitting Illustration Credit: KyotoU/Nobuko Naka |
Besides being "a girl's best friend," diamonds have broad industrial applications, such as in solid-state electronics. New technologies aim to produce high-purity synthetic crystals that become excellent semiconductors when doped with impurities as electron donors or acceptors of other elements.
These extra electrons -- or holes -- do not participate in atomic bonding but sometimes bind to excitons -- quasi-particles consisting of an electron and an electron hole -- in semiconductors and other condensed matter. Doping may cause physical changes, but how the exciton complex -- a bound state of two positively-charged holes and one negatively-charged electron -- manifests in diamonds doped with boron has remained unconfirmed. Two conflicting interpretations exist of the exciton's structure.
An international team of researchers led by Kyoto University has now determined the magnitude of the spin-orbit interaction in acceptor-bound excitons in a semiconductor.
"We broke through the energy resolution limit of conventional luminescence measurements by directly observing the fine structure of bound excitons in boron-doped blue diamond, using optical absorption," says team leader Nobuko Naka of KyotoU's Graduate School of Science.