. Scientific Frontline: Optical Fibers with Unusual Properties Created in Russia

Monday, August 8, 2022

Optical Fibers with Unusual Properties Created in Russia

Credit: Vladimir Petrov

Researchers of the Science Lab of Fiber Technology and Photonics at Ural Federal University have developed and produced infrared optical fibers with unique properties. The fibers are nontoxic and, as studies have shown, retain their outstanding properties when treated with ionizing beta radiation by doses up to 1 MGy. The team of scientists published an article describing the research, properties and areas of application of the obtained fibers in the scientific journal Optical Materials.

"This opens up the prospect of application of light guides made of the obtained fibers in conditions of intense ionizing radiation. That is, not only in the traditional field of optoelectronics, but also in laser surgery, endoscopic and diagnostic medicine, in determining the composition of hazardous waste from the nuclear industry, and in space," lists Liya Zhukova, Chief Scientist of the Laboratory, Professor of the Department of Physical Chemistry and Chemistry of Colloids at UrFU.

Because the fibers are capable of receiving and transmitting radiation from space objects, they can be embedded in infrared space telescopes, replacing massive mirrors and lenses. The lifespan of the fibers will be longer than the life cycle of the telescopes themselves, the developers claim.

Fibers are also highly productive in the non-hazardous for humans terahertz radiation region (between the region of mid- and far-infrared radiation, on the one hand, and microwave radiation, on the other hand). This means that fiber optic cables are suitable for creating equipment that could become a safe substitute for magnetic resonance imaging and x-rays - in medicine or in the process of pre-boarding scanning of passengers and their luggage. It would not require the use of cumbersome and expensive metal detectors, and passengers would not even feel that they are being screened.

Loading feedstock into the device where the crystal will grow.
From left to right: Polina Pestereva, / Aleksandr Lvov / Dmitry Salimgareev
Credit: Vladimir Petrov

The fibers are based on crystals of the AgBr-AgI system. At the first stage of development, using an environmentally friendly, waste-free and energy-saving method developed by Liya Zhukova, chemists from UrFU synthesized a charge of almost one hundred percent purity and for the first time in the world grew silver bromide and silver iodide monocrystals from it.

"The grown crystals have extremely high transparency, plasticity, as well as photostability and non-hygroscopicity - the ability to retain their properties under the influence of light without interacting with moisture," explains Anastasia Yuzhakova, a Junior Researcher at the Ural Federal University's Science Lab of Fiber Technology and Photonics.

Using computer modeling, the colleagues determined the optimal conditions for manufacturing homogeneous infrared optical fibers with unique characteristics from monocrystals.

The experiment confirmed the validity of the computer simulation results. The fibers were successfully produced using unique proprietary technologies and equipment from cylindrical blanks with improved optical and mechanical properties due to chemical pretreatment. The blanks were extruded - pressed through a forming hole. The presence of iodine anions in the crystal lattice of silver bromide determined additional photo- and radiation resistance of the fibers, expanded the range of their infrared radiation transmission.

"Based on monocrystals of AgBr-AgI system we created optical fibers with the widest infrared transmission range to date - from 3 to 25 microns. The transparency of the fibers reaches 70-75%, which corresponds to theoretically possible values for crystals of AgBr-AgI system. At the same time, the optical losses of the fibers reach extremely low values," Anastasia Yuzhakova describes.

In the future, the co-authors of the article intend to study and illuminate in detail the nature of the high radiation resistance in crystals of the AgBr-AgI system and fibers based on them.

It should be noted that the development of fibers and the creation of new functional materials is one of the research areas in the Ural Federal University supported within the state program "Priority 2030" in the direction of "Functional Inorganic, Hybrid Materials and Technologies of Detector Technology and Photonics".

The research is conducted under the supervision of Liya Zhukova and the leading specialist of the Laboratory, Professor of the Department of Physical Chemistry and Chemistry of Colloids Aleksandr Korsakov. This work was supported by a grant from the Russian Science Foundation (project № 21-73-10108, supervised by Dmitry Salimgareev, Laboratory Researcher).

Source/Credit: Ural Federal University


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