Ice dissolves iron faster than liquid water

When ice freezes and thaws repeatedly, chemical reactions are fuelled that can have significant impact on ecosystems. The photo was taken in Stordalen, Abisko.
Photo Credit: Jean-François Boily

Ice can dissolve iron minerals more effectively than liquid water, according to a new study from Umeå University. The discovery could help explain why many Arctic rivers are now turning rusty orange as permafrost thaws in a warming climate.

The study, recently published in the scientific journal PNAS, shows that ice at minus ten degrees Celsius releases more iron from common minerals than liquid water at four degrees Celsius. This challenges the long-held belief that frozen environments slow down chemical reactions.

“It may sound counterintuitive, but ice is not a passive frozen block,” says Jean-François Boily, Professor at Umeå University and co-author of the study. “Freezing creates microscopic pockets of liquid water between ice crystals. These act like chemical reactors, where compounds become concentrated and extremely acidic. This means they can react with iron minerals even at temperatures as low as minus 30 degrees Celsius.”

Angelo Sebaaly, doctoral student at the
Department of Chemistry.
Photo Credit: Giacomo Gorza

Releases organic compounds

To understand the process, the researchers studied goethite – a widespread iron oxide mineral – together with a naturally occurring organic acid, using advanced microscopy and experiments.

They discovered that repeated freeze-thaw cycles make iron dissolve more efficiently. As the ice freezes and thaws, organic compounds that were previously trapped in the ice are released, fueling further chemical reactions. Salinity also plays a crucial role: fresh and brackish water increase dissolution, while seawater can suppress it.

From mines to the atmosphere

The findings apply mainly to acidic environments, such as mine drainage sites, frozen dust in the atmosphere, acid sulfate soils along the Baltic Sea coast, or in any acidic frozen environment where iron minerals interact with organics.

The next step is to find out if the same is true for all iron-bearing ice. This is what ongoing research in the Boily laboratory will soon reveal.

“As the climate warms, freeze-thaw cycles become more frequent,” says Angelo Pio Sebaaly, doctoral student and first author of the study. “Each cycle releases iron from soils and permafrost into the water. This can affect water quality and aquatic ecosystems across vast areas.”

The findings show that ice is not a passive storage medium, but an active player. As freezing and thawing increase in polar and mountain regions, for the impact on ecosystems. and the natural cycling of elements could be significant.

Published in journal: Proceedings of the National Academy of Sciences

Title: Ice as a kinetic and mechanistic driver of oxalate-promoted iron oxyhydroxide dissolution

Authors: Angelo P. Sebaaly, Frank van Rijn, Khalil Hanna, and Jean-François Boily

Source/Credit: Umeå University | Sara-Lena Brännström

Reference Number: chm092225_01

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