Tiny materials hold big mysteries, the solutions to which could bring about next-generation electronics. An international collaboration led by researchers based in Japan has solved the whodunit of cryptic overtone signals in an analysis of molybdenum diselenide, an atomically thin crystal lattice with desirable properties unique from its bulkier three-dimensional form.
They published their results in Nature Communications.
The compound belongs to a family of similarly two-dimensional semiconductors called transitional metal dichalcogenide (TMD) monolayers, all of which have electronic band structures containing so-called valleys. TMD lattices are organized as hexagons, with the corresponding wavevector, known as k-space, along the side. The side center point of the k-space is known as the “M point” and the six corners as “K (-K) points.” The valleys are the dips and rises of the electronic band at the corners of the hexagons, where energy or information-carrying particles can move to tip the material to action. The intervalley activities, especially as related to electron scattering, have remained elusive, though. In this process, phonons, or units of energy manifested as vibrations, cause the electrons to disperse and transition states in the intervalley space at ultrafast speed.