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Scientists from Duke University and ORNL used neutron scattering to see how lithium ions, represented by the glowing orbs, move through a diffusion gate, represented by the gold triangle, in a solid-state electrolyte. Image Credit: Phoenix Pleasant/ORNL, U.S. Dept. of Energy |
A team of scientists led by a professor from Duke University discovered a way to help make batteries safer, charge faster and last longer. They relied on neutrons at the Department of Energy’s Oak Ridge National Laboratory to understand at the atomic scale how lithium moves in lithium phosphorus sulfur chloride (Li6PS5Cl), a promising new type of solid-state battery material known as a superionic compound.
Using neutrons at ORNL’s Spallation Neutron Source (SNS), and machine-learned molecular dynamics simulations at the National Energy Research Scientific Computing Center at Lawrence Berkeley National Laboratory, they found that lithium ions easily diffused in the solid material, as they do in liquid electrolytes, allowing faster, safer charging. The results, published in Nature Physics, could bring the best of both worlds for solid-state electrolytes, or SSEs, enabling next-generation batteries.
“Our research was about figuring out what is going on inside these materials using the power of neutron scattering and large-scale computer simulations,” said Olivier Delaire, associate professor of mechanical engineering, materials science, chemistry and physics at Duke University. Delaire arrived at ORNL in 2008 as a Clifford G. Shull Fellow and won DOE’s Office of Science Early Career Award in 2014. Today, he leads a research group at Duke dedicated to investigating the atomic structure and dynamics of energy materials.